Direct alcohol fuel cells dafcs have attracted enormous attention as powerful sources for portable electronic devices and transportation due to the much higher energy density than gaseous fuels such as. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline. The ethanol oxidation reaction and product distributions in a. Bio ethanol based fuel cells may improve the welltowheel balance of this biofuel because of the increased conversion rate of the fuel cell compared to the internal combustion engine. However, there exists a large overpotential toward urea electrooxidation. Direct alcohol fuel cells dafcs are a type of proton exchange membrane fuel cell in which. This power density is about four times higher than any other sofc. The direct ethanol fuel cell performance scientific. The performance of three alkaline direct ethanol fuel cells adefcs is investigated. Pdf direct ethanol fuel cells defcs are attractive as a power source options because ethanol is a nontoxic. Special attentions are given to direct ethanol fuel cells defcs and direct methanol fuel cells dmfcs. The results showed that fuel cells have a high performance at high concentration. Ethanol is a product of fermentation in fermentation, ethanol retains much of the energy that was originally in the sugar, which explains why ethanol is an excellent fuel.
Kyushu institute of technology research group proposes using ethanol as a direct fuel in nextgeneration fuel cells. The fuel cell stack utilizes a hydrogen rich gas stream, and there are several approaches to supplying the hydrogen onboard the vehicle. Files available from the acs website may be downloaded for personal use only. Since publication of the first edition of fuel cell systems explained, three compelling drivers have supported the continuing development of fuel cell technology. Jun 06, 2012 a peak power density of more than 400 mwcm 2 was achieved at 800c with air and a fuel containing 7. The effect of various operating parameters like cell temperature, ethanol solution flow rate, ethanol concentration, anode diffusion layer, and oxygen flow rate were studied using ptresn 20. This system was shown to have many advantages over previously reported methodologies such as. A passive direct formate fuel cell using ambient air is designed, fabricated, and tested. But real world figures may be only achieved in some years since the development of direct methanol and ethanol fuel cells is lagging behind hydrogen powered fuel. Pdf direct ethanol fuel cells defcs are a promising carbonneutral and sustainable power source for portable, mobile, and. A direct methanol fuel cell dmfc is an electrochemical cell that generates electricity based on the oxidation of methanol and reduction of oxygen.
A direct alcohol fuel cell and surface science perspective. Defc stack was also constructed using these electrocatalysts and etched printed circuit boards as anode and cathode current collectors. An isolated platinum wire connected to the edge of the flow fields acted as a current collector and was put under the mica sheet. Defc uses ethanol in the fuel cell instead of the more toxic methanol. Direct ethanol fuel cells defcs, which use ethanol as a fuel, have attracted considerable attention due to their relatively high energy density, the nontoxicity of ethanol, and the abundance of ethanol sources. Direct alcohol fuel cells an overview sciencedirect topics. The third edition of fuel cell systems explained is an updated version of a book that has always been essential reading for everyone. Direct ethanol pemfuel cells performance on binary catalysts direct ethanol fuel cell operation over different bimetallic anode catalysts at 90 c. Direct ethanol fuel cells are able to burn ethanol without first reforming it to hydrogen.
Direct ethanol fuel cells with superior ethanoltolerant. Ethanol and air are used as their fuel to power up their devices. Geometrically controlled nanoporous pdau bimetallic catalysts. Direct catalytic methanoltoethanol photoconversion. The direct ethanol oxidation basedceramic membrane.
Nickel is an ideal nonnoble metal anode catalyst for direct urea fuel cell dufc due to its high activity. Electrical performances and reaction products distribution under operating conditions with different platinumbased anodes. Ive seen a lot of fuel cells that run on methanol, but the igen data sheet pdf was the first time ive seen a company make specific promises about both power output and fuel consumption. Direct methanol fuel cell their main advantage is the ease of transport of methanol, an energydense yet reasonably stable liquid at all environmental conditions. Doped diamond for direct ethanol fuel cell applications dr.
High electrocatalytic performance of graphene nanoribbon supported ptau nanoalloy for direct ethanol fuel cell and theoretical analysis of antico poisoning. The direct methanol fuel cell dmfc enables the direct conversion of the chemical energy stored in liquid methanol fuel to electrical energy, with water and carbon dioxide as byproducts. This type of direct ethanol fuel cell yielded an opencircuit voltage ocv of 1. Fuel cells are of tremendous interest, from both energy and environmental considerations. Anode catalyst of 20% ptceo 2c was prepared by colloidal method using ethylene glycol as the reductant. The porous silicon carbide sic membrane, fabricated through sintering process, was applied for the fabrication of defc.
Direct ethanol fuel cell using hydrotalcite clay as a. Begin the process in the ethanolwater mix container then transfer this solution into the fuel cell via silicon tubing where it will be converted into electrical. Direct methanol fuel cell dmfc performanceworcester polytechnic institute. Leading researchers from universities, government laboratories and fuel cell industries in north america, europe and asia share their knowledge and information on recent advances in. A micro alkaline direct ethanol fuel cell with platinumfree catalysts. Direct ethanol fuel cell defc assembled with ceramic.
Efficiency is quite low for these cells, reaching around 10% 1, so they are targeted especially to portable applications, where energy and power density are more important than. Directethanol fuel cells or defcs are a category of fuel cell in which ethanol is fed directly into. Analysis of a permselective membranefree alkaline direct. Directmethanol fuel cell their main advantage is the ease of transport of methanol, an energydense yet reasonably stable liquid at all environmental conditions. Pdf direct ethanol fuel cell defc fabricated with ceramic. Download product flyer is to download pdf in new tab. A selective electrocatalystbased direct methanol fuel cell operated at high concentrations.
These blends can be varied over time, providing fuel source flexibility. The performance of the defc was found to be increased by. Jun 14, 2016 the greater range comes from the more efficient process of reforming ethanol into hydrogen and using that in a fuel cell to produce electricity, which generates more energy to turn the wheels than. Comparison of alkaline direct ethanol fuel cells with and without. Experimental investigation of a passive direct ethanol fuel cell. Apr 22, 2014 ethanol is a product of fermentation in fermentation, ethanol retains much of the energy that was originally in the sugar, which explains why ethanol is an excellent fuel. Users are not otherwise permitted to reproduce, republish. A physical model is developed to study the coupled mass and charge transport in a permselective membranefree alkaline direct ethanol fuel cell. Oct 03, 2017 direct ethanol fuel cell for portable power. The techniques of cyclic voltammetry, anode polarization curve and single direct ethanol fuel cell defc tests were used to evaluate and compare the.
This type of fuel cell is not only free of expensive ion exchange membranes and platinum based catalysts, but also features a facile oxygen reduction reaction due to the presence of alkaline electrolyte. Several technologies currently use biomass as feedstock to generate electricity through combustion, gasification, solid oxide fuel cell sofc, microbial fuel cell mfc 10, 11 and direct carbon fuel cell dcfc 12. Two important features can be obtained with the use of this membrane. Mavrokefalos department of chemistry, chemistry research laboratory, university of oxford, mansfield road, oxford, ox1 3ta england, uk. This system consisted of a nondispersive infrared co. Effective octane and efficiency advantages of direct. A novel online system for quantifying product distributions of ethanol oxidation in direct ethanol fuel cells was developed. Direct injection engines using ethanol as either the primary fuel or as an octane boosting fuel could thus provide approximately the same efficiency gain as turbocharged diesels or typical hybrid gasolineelectric powertrains. Direct ethanol fuel cells def cs linkedin slideshare. Wed like to understand how you use our websites in order to improve them.
Ethanol fuel is ethanol ethyl alcohol, the same type of alcohol found in alcoholic beverages. Due to the lack of the cc bond present in higher alcohols, methanol is the alcohol with. Study on the performance of the micro direct ethanol fuel cell. They have been used as a model to investigate a range of fuel cell concepts including the use of pem. Nickelcobalt bimetallic anode catalysts for direct urea fuel. Eos direct ethanol fuel cell is one of product of ndc power that uses nonplatinum catalysts for anode and cathode. Protonexchangemembranebased direct ethanol fuel cell single cell tests with online ms analytics of the anolyte for single cells with a ptsnc anode with 3. Flow fuel cell powered by combustible agricultural waste. The major benefit to this type of fuel cell is that an ethanol supply chain is already available and there are a number of sources from which ethanol can be generated. The ethanol fuel cell science kit shows the workings of a direct ethanol fuel cell and the principles behind the conversion of ethanol into electrical energy through oxidization. An aqueous methanol solution of low molarity acts as the reducing agent that traverses the anode flow field. Ptresn as metal catalysts for electrooxidation of ethanol. Box 880 morgantown, west virginia 265070880 november 2004.
Direct ethanol fuel cells defcs are a promising carbonneutral and sustainable power source for portable, mobile, and stationary applications. This first book to focus on a comprehensive description on dmfc electrocatalysis draws a clear picture of the current status of dmfc technology, especially the advances, challenges and perspectives in the field. Nickelcobalt bimetallic anode catalysts for direct urea. Development of anode catalyst for a direct ethanol fuel cell article pdf available in journal of applied electrochemistry 344.
A methyl carbene reaction intermediate is observed during the conversion, and the method enables access to the more useful as both. Direct ethanol fuel cell defc has been assembled with the ceramic membrane basedptc 40wt% catalyst electrodes. A directmethane fuel cell with a ceriabased anode nature. However, since the crossover of ethanol as a fuel in defcs can deteriorate the cell performance due to the oxidation of ethanol etoh at the cathode during oxygen reduction reaction. Geometrically controlled nanoporous pdau bimetallic. The direct ethanol fuel cell defc is selected for this research. Introduction to biofuel university of california, berkeley. Bhatia, in advanced renewable energy systems, 2014. However, conventional defcs that use acid protonexchange membranes typically nafion type and platinumbased catalysts exhibit low performance i. The incremental cost for this efficiency gain is a fraction of the incremental cost for these two high efficiency options. Direct alcohol fuel cells dafcs have attracted enormous attention as powerful sources for portable electronic devices and transportation due to the much higher energy density than gaseous fuels such as hydrogen and natural gas. The ethanol oxidation reaction and product distributions. Enhanced mass activity and stability of bimetallic pd.
The effect on performance of single direct ethanol cell due to ethanol solution concentrations 5%, 10% and 15% by volume, ambient temperature and, continuously changing of ambient temperature and, load resistance and and air circulation through the cell were investigated experimentally in this research. Pdf development of anode catalyst for a direct ethanol. Most cars on the road today in the united states can run on blends of up to 10 per cent ethanol, and the use of 10 per cent ethanol gasoline. Electrochemical characterization of lowtemperature direct. This conversion is achieved with no solvent, ligand, additive, heating, atmosphere, or pressurizationjust with light irradiation. Ethanol electrooxidation on ptceo 2c catalyst in direct ethanol fuel cell hariyanto1, widodo w. In the case of polymerelectrolyte fuel cells, which have been studied for vehicle applications, the direct use of methanol fuel has been reported, but resulted in fuel permeating the electrolyte1,2. Pdf an alkaline direct ethanol fuel cell with a cation. Aug 29, 2014 nickel is an ideal nonnoble metal anode catalyst for direct urea fuel cell dufc due to its high activity.
The greater range comes from the more efficient process of reforming ethanol into hydrogen and using that in a fuel cell to produce electricity. Pdf performance of a passive direct ethanol fuel cell. It remarkably use for portable application such as pda, laptop and phone as shown in fig. Ethanol electrooxidation on ptceo2 direct ethanol fuel cell.
Pdf a micro alkaline direct ethanol fuel cell with. Ethanol powered fuel cells up to now have had a number of drawbacks including low catalytic performance, poor fuel cell efficiency, and a decrease in open voltage due to ethanol crossover when the ethanol concentration was increased to boost efficiency. A photodriven direct methanoltoethanol conversion is reported with a robust gallium nitride catalyst under ambient conditions. Principles of direct methanol fuel cells for portable and. Mica filled ptfe was used to border the flow field. Fuel cell test single cell tests were performed with a cell made of titanium having a crosssectional area of 1 x 1 cm gold coated parallel flow field. Ethanol from cellulose cellulosean organic compound that is the structural component of cell walls for plants. Fundamentals of electrochemistry with application to direct alcohol. Department of energy office of fossil energy national energy technology laboratory p. The dilute ethanolwater fuel solution was used for the defc operation with a micropump and air blower. Electricity generation from biomass is commercially produced by combustion or gasification using a steam turbine. Polymer electrolyte fuel cells 17 pefc 17 materials for alkaline fuel cells and directfuel fuel cells.